Ordered Binary Decision Diagrams (OBDDs, in short) are useful representations for Boolean functions and are applied in various fields such as design and formal verification of digital sys- tems, combinatorics and artificial intelligence. This paper discusses relationships between the two OBDDs of a monotone function and of the set of its prime implicants by comparing their subfunctions. First, we analyze the OBDDs of the characteristic function of stable sets of a graph, which is a monotone Boolean function, and of the family of all the maximal stable sets, which corresponds to the set of all the prime implicants of that function. As a result we show that there exists a monotone function which has an O(n) size DNF but cannot be represented by a polynomial size OBDD. In other words, we cannot obtain the OBDD of the set of all the prime implicants of a monotone function in an output-size sensitive manner once we have constructed the OBDD of that function in the worst case. This gives a negative answer to open questions by Coudert [3] who has given an implicit method to compute the set of prime implicants of a Boolean function by using OBDDs for the two-level logic minimization. A positive result is also given for a meaningful class of matroid functions.